[(TeMe2)Mn(CO)4(5-Te)(4-Te)Mn4(CO)12]: A Pentacoordinate Bridging Tellurido Ligand in a Square-Pyramidal Geometry

Autor:	Horng Sun Chen, Minghuey Shieh, Huey Yea Yang, Chuen Her Ueng
Rok vydání:	1999
Předmět:	Crystallography Octahedral cluster Chemistry Inorganic chemistry Cluster (physics) chemistry.chemical_element General Chemistry Manganese Thermal reaction Tellurium Catalysis Square pyramidal molecular geometry Ion
Zdroj:	Angewandte Chemie International Edition. 38:1252-1254
ISSN:	1521-3773 1433-7851
DOI:	10.1002/(sici)1521-3773(19990503)38:9<1252::aid-anie1252>3.0.co;2-a
Popis:	The first Te-Mn-CO clusters were obtained by the thermal reaction of K2 TeO3 with [Mn2 (CO)10 ] in MeOH. The basicity of the μ4 -Te ligand in the octahedral cluster anion [(μ4 -Te)2 Mn4 (CO)12 ]2- is demonstrated by its binding to the fragment [(TeMe2 )Mn(CO)4 ]+ in an axial fashion to afford the novel cluster 1.
Databáze:	OpenAIRE
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