In situ preparation of lithographic resists containing glutarimide groups

Autor:	L. W. Welsh, Edward Gipstein, Hiroyuki Hiraoka, Joachim Bargon
Rok vydání:	1978
Předmět:	Materials science Polymers and Plastics Methylamine General Chemistry Isocyanate Surfaces Coatings and Films chemistry.chemical_compound chemistry Methacrylic acid Polymer chemistry Materials Chemistry Organic chemistry Solubility Ethylamine Methyl methacrylate Imide Acrylic acid
Zdroj:	Journal of Applied Polymer Science. 22:3397-3403
ISSN:	1097-4628 0021-8995
DOI:	10.1002/app.1978.070221205
Popis:	Poly(acrylic acid) and poly(methacrylic acid) homopolymers, copolymers, and 1-μ-thick films have been converted in high yield to their corresponding cyclic imide derivatives by an in situ gas–solid phase reaction at 200°C with ammonia, methylamine, and ethylamine, respectively. Under similar reaction conditions with H2S or CH3SH as the reactive gas, sulfur was incorporated into the polymers in low yield. Under UV and electron beam irradiation, these cyclic derivatives degraded with main chain scission to eliminate isocyanic acid or alkyl isocyanate and to form olefins and ketenes. Poly(diacrylimide) was the exception and crosslinked. The poor solubility in organic solvents and the very high solubility in aqueous solutions of base limited the use of these films as positive resists. However, poly(methyl methacrylate) copolymers, containing 20%–25% cyclic groups, exhibited adequate solubility and sensitivity to be utilized as lithographic resists.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7757a7df4c46f3dcb95642a598b1dd8a https://doi.org/10.1002/app.1978.070221205 Zobrazit plný text záznamu Plný text