A Facile Synthesis of a Push‐Pull Mixed‐Ligand Pd‐Dithiolene Complex Containing the Et 2 timdt Ligand (Et 2 timdt = Monoreduced Diethylimidazolidine‐2,4,5‐trithione)

Autor:	Emanuela Grigiotti, Francesco Isaia, M. Carla Aragoni, Vito Lippolis, J. Derek Woollins, Piero Zanello, Francesco A. Devillanova, Carla Denotti, Massimiliano Arca, Franco Laschi, Alexandra M. Z. Slawin, Luca Pala
Rok vydání:	2003
Předmět:	Inorganic Chemistry chemistry Stereochemistry Ligand Polymer chemistry chemistry.chemical_element Halogenation Mixed ligand Push pull Palladium
Zdroj:	European Journal of Inorganic Chemistry. 2003:1291-1295
ISSN:	1099-0682 1434-1948
DOI:	10.1002/ejic.200390165
Popis:	The reaction of the dithiolene [Pd(Et2timdt)2] (Et2timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br2 or IBr yields the complex [Pd(Et2timdt)Br2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et2timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::773edb2ee65262751f5be9ceba4bcfb9 https://doi.org/10.1002/ejic.200390165 Zobrazit plný text záznamu Plný text