Fast Pyrolysis of Opuntia ficus-indica (Prickly Pear) and Grindelia squarrosa (Gumweed)

Autor: Bishnu Neupane, Bryon S. Donohoe, Calvin Mukarakate, Daniel Carpenter, Phillip Cross, John C. Cushman, Jesse A. Mayer, Glenn C. Miller, Mark R. Nimlos, Sushil Adhikari
Rok vydání: 2018
Předmět:
Zdroj: Energy & Fuels. 32:3510-3518
ISSN: 1520-5029
0887-0624
DOI: 10.1021/acs.energyfuels.7b03752
Popis: Opuntia ficus-indica (prickly pear) and Grindelia squarrosa (gumweed) are two exceptionally drought tolerant plant species capable of growing in arid and semiarid environments. Additionally, they have unique cell wall structures. Prickly pear contains pectin and high levels of ash (16.1%) that is predominantly Ca and K. Gumweed has high levels of extractives that contain grindelic acid and monoterpenoids. The objective of this paper was to evaluate how these unique cell wall components alter the pyrolysis performance of prickly pear and gumweed. Using a tandem micropyrolyzer with GC-MS/FID/TCD, a detailed account of the product slate is given for products generated between 450 and 650 °C. Pyrolysis of prickly pear showed that the high levels of ash increase the amount of organics volatilized and shifted product pools, making it possible to generate up to 7.3% carbonyls vs 3.8% for Pinus taeda (loblolly pine) and 10.5% hydrocarbons vs 1.8% for pine depending on reaction conditions. Pyrolysis of gumweed sho...
Databáze: OpenAIRE