Kinetic and Thermodynamic Specific Features of Hydrogenation of Hexene-1, Heptene-1, and Cyclohexene on Catalyst Containing Copper Nanoparticles
| Autor: | R. V. Shafigulin, Alexander A. Shmelev, Elena O. Filippova, A. V. Bulanova, N. S. Filimonov |
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| Rok vydání: | 2017 |
| Předmět: |
General Chemical Engineering
Activated complex Cyclohexene chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Heptene Copper 0104 chemical sciences Catalysis chemistry.chemical_compound Nickel chemistry Hexene 0210 nano-technology Benzene |
| Zdroj: | Russian Journal of Applied Chemistry. 90:1648-1654 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427217100147 |
| Popis: | Kinetics of hydrogenation of hexene-1, heptene-1, and cyclohexene on copper nanoparticles was studied. To examine the thermodynamic specific features, the entropy of formation of an activated complex, rate constants, and conversion were calculated. A conclusion that the key role is played by the entropy factor in the formation of the activated complex is made on the basis of the data obtained. The similarity between the mechanisms by which activated complexes are formed in the hydrogenation of hexene-1, heptene-1, and cyclohexene and in that of hexyne-1, hexadiene-1,5, and benzene with the use of nickel nanoparticles was confirmed. The results obtained enable a conclusion about the high catalytic activity of copper nanoparticles in reactions of hydrogenation of unsaturated hydrocarbons in the temperature range 140–200°C at a pressure of 2 atm. |
| Databáze: | OpenAIRE |
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