Transition metal-free oxidation of activated alcohols to aldehydes and ketones in 1,1,1,3,3,3-hexafluoro-2-propanol
| Autor: | Saeed Mohammadzadeh Talesh, Samad Khaksar |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Allylic rearrangement Organic Chemistry Biochemistry Hexafluoro-2-propanol Aldehyde Catalysis Inorganic Chemistry Solvent chemistry.chemical_compound chemistry Transition metal Sodium hypochlorite Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Journal of Fluorine Chemistry. 140:95-98 |
| ISSN: | 0022-1139 |
| DOI: | 10.1016/j.jfluchem.2012.05.017 |
| Popis: | A simple and convenient procedure for the oxidation of various benzylic, allylic and some aliphatic alcohols to their corresponding carbonyl compounds is described using sodium hypochlorite as the oxidant in 1,1,1,3,3,3-hexafluoro-2-propanol without use of a catalyst or any other additive. The solvent can be readily recovered from reaction products in excellent purity for direct reuse. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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