(η5-Pentaphenylcyclopentadienyl){1-(η6-phenyl)-2,3,4,5-tetraphenylcyclopentadienyl} iron(II), [Fe(η5-C5Ph5){(η6-C6H5)C5Ph4}], a linkage isomer of decaphenylferrocene

Autor:	Anthony F. Masters, Peter A. Lay, Leslie D. Field, Charles M. Lindall, Kylie N. Brown
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Argon Stereochemistry chemistry.chemical_element Protonation Zinc Medicinal chemistry chemistry.chemical_compound Hydrocarbon chemistry Sandwich compound Molecular Medicine Linkage isomerism Benzene
Zdroj:	J. Chem. Soc., Chem. Commun.. :408-410
ISSN:	0022-4936
Popis:	Reaction between [Fe(CO)5], zinc dust, and bromopentaphenylcyclopentadiene in refluxing benzene under argon affords (η5-pentaphenylcyclopentadienyl){1-(η6-phenyl)-2,3,4,5-tetraphenylcyclopentadienyl}iron(II), [Fe(η5-C5Ph5){(η6-C6H5)C5Ph4}], a linkage isomer of decaphenylferrocene, with a novel, zwitterionic structure; the compound is readily protonated to give [Fe(η5-C5Ph5){(η6-C6H5)HC5Ph4}]+X–.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::76e83b330b69fcbd5c4a40aea01ec9e5 https://doi.org/10.1039/c39900000408 Zobrazit plný text záznamu