Sodium 2-methyl-2-propylthiolate, a versatile sulfur reagent. Preparation of protected polysulfur ligands and their nickel(II) complexes

Autor:	Jan Becher, Hans Toftlund, C. E. Stidsen, Fahmy M. Asaad
Rok vydání:	1986
Předmět:	Inorganic Chemistry Nickel chemistry Reagent Sodium Materials Chemistry Nucleophilic substitution Chlorine chemistry.chemical_element Organic chemistry Physical and Theoretical Chemistry Sulfur Ion
Zdroj:	Inorganica Chimica Acta. 121:23-26
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(00)87734-8
Popis:	Multisulfur-containing ligands can conveniently be prepared by nucleophilic substitution of chlorine in various heterocyclic and other aromatic systems by the 2-methyl-2-propylthiolate anion, followed by elimination of isobutene from the resulting t-butylthioethers. The preparation of bis(3-thiolato-2(1H)-pyrazinethione)-nickelat(II) ( 5a ) by this methodology is described.
Databáze:	OpenAIRE
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