Raman and infrared studies of the sharp 890 CM −1 mode in organic superconductors
Autor: | Hau H. Wang, Yuankun Lin, Aravinda M. Kini, John E. Eldridge, John A. Schlueter |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Molecular Crystals and Liquid Crystals. 380:93-100 |
ISSN: | 1563-5287 1542-1406 |
DOI: | 10.1080/713738720 |
Popis: | Raman and infrared spectra of several organic superconductors are presented, showing some unusual behaviours of a sharp line at 890 cm −1 in both spectra. These include a frequency shift below T c , a positive deuterium isotope shift, frequency softening at low temperatures and sensitivity to lattice superstructure. It is proposed that either the ion or the neutral molecule has a distortion with a strong ν 60 (B 3g ) mode component. |
Databáze: | OpenAIRE |
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