Critical analysis of the effect of transport phenomena and operational parameters on the performance of an intermediate-scale surface fluorination reactor
| Autor: | David Lokhat, Inbanathan Govender, Matthew Lasich, L. D. Kock, Deresh Ramjugernath |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
business.product_category
010405 organic chemistry Chemistry Organic Chemistry Infrared spectroscopy Factorial experiment Permeation 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Inorganic Chemistry Chemical engineering Mass transfer Bottle Environmental Chemistry Gravimetric analysis High-density polyethylene Physical and Theoretical Chemistry business Transport phenomena |
| Zdroj: | Journal of Fluorine Chemistry. 237:109617 |
| ISSN: | 0022-1139 |
| Popis: | An intermediate-scale fluorination system, capable of undertaking fluorination at sub atmospheric pressure—up to 348 K under static and dynamic conditions—comprising a 112 L reactor was designed, constructed and commissioned. The fluorination system is capable of producing more realistic flow patterns—along with heat and mass transfer effects—which could be better used to evaluate various fluorination recipes. A factorial design of experiment was used to perform fluorination tests using commercially produced 100 mL high density polyethylene (HDPE) bottles. The effect of bottle position within the reactor and the effect of fluorination on the characteristics of the bottles was investigated using gravimetric analysis, Infrared Spectroscopy (IR), and permeation tests. |
| Databáze: | OpenAIRE |
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