Micellar Electrokinetic Chromatographic Analysis of Historic Dyes and Their Photofading Products

Autor:	Justin Goodwin, Aimee Dervishian, Connor King, Christine L. Copper
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Electrokinetic phenomena Chromatography Chemistry Organic Chemistry Clinical Biochemistry Sodium Cholate Acetonitrile Chemical company Biochemistry Analytical Chemistry
Zdroj:	Chromatographia. 84:979-983
ISSN:	1612-1112 0009-5893
DOI:	10.1007/s10337-021-04080-5
Popis:	Since the early 20th century, the Monroe Chemical Company’s Putnam Fadeless Dyes were used by consumers to dye numerous types of textiles. In this work, we describe a novel micellar electrokinetic chromatographic (MEKC) method employing sodium cholate and acetonitrile in the background electrolyte that can be used to analyze these dyes. Specifically, Putnam Fadeless Dyes were successfully extracted from linen samples colored with them and the components of each dye were separated and detected using MEKC. These results compared favorably to MEKC data from standard dye solutions. Dyed linen samples were also exposed to simulated sunlight and MEKC was used to analyze dyes extracted from them. The resulting data showed that photofading altered the amount of dye in the fabric but not its chemical composition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::768edecf9273463b057d18dd56d5b9c5 https://doi.org/10.1007/s10337-021-04080-5 Zobrazit plný text záznamu Full text from SpringerLink