Hydroformylation of styrene in the presence of platinum(II) complex catalysts incorporating cyclic phosphines and phosphonous diesters as P-ligands

Autor:	Andrea Kerényi, László Kollár, Péter Pongrácz, Viktória Ujj, Viktória Barbara Kovács, György Keglevich
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Denticity Organic Chemistry Phosphole Regioselectivity Biochemistry Aldehyde Styrene Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Chelation Physical and Theoretical Chemistry Hydroformylation
Zdroj:	Journal of Organometallic Chemistry. 696:2234-2237
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2010.11.045
Popis:	The hydroformylation activity of various 5- and 6-membered P -heterocycles was investigated in platinum-catalysed hydroformylation of styrene. All of the tested ligands, such as the phosphole-, oxaphosphorine- and phoshinine-based ligands proved to be catalytically active. Especially good aldehyde selectivities were obtained with the chelating diphenylphosphino-tetrahydrophosphinine and diphenylphosphino-hexahydrophosphinine ligands. While the two aldehyde regioisomers were formed close to equimolar amounts with the monodentate ligands, high branched selectivities were observed with the chelating ones. The effect of the 4-substitution of the parent styrene on chemo- and regioselectivity was investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7672b8ae410c91326cdc6db12254d108 https://doi.org/10.1016/j.jorganchem.2010.11.045 Zobrazit plný text záznamu Full Text from ScienceDirect