Iminoacetonitrile, an HCN dimer; I.R. identification in an argon matrix

Autor:	Gerhard Raabe, Curt Wentrup, Juliusz J. Radziszewski, P. Lorencak
Rok vydání:	1986
Předmět:	Argon Infrared Dimer Photodissociation Matrix isolation chemistry.chemical_element Photochemistry Spectral line Isotopomers Matrix (chemical analysis) chemistry.chemical_compound chemistry Molecular Medicine Physical chemistry
Zdroj:	Journal of the Chemical Society, Chemical Communications. :916
ISSN:	0022-4936
DOI:	10.1039/c39860000916
Popis:	The E- and Z-forms of iminoacetonitrile, HNCH–CN, are formed by 308 nm photolysis of azidoacetonitrile in an Ar matrix at 11 K and identified by their i.r. spectra and the observed isotopic shifts in the 15N isotopomers; a previous claim of the formation of the corresponding isonitrile, HNCH–NC, is shown to be erroneous.
Databáze:	OpenAIRE
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