The rate constant of the F + NH3 reaction: Inverse temperature dependence

Autor:	Avigdor Persky
Rok vydání:	2007
Předmět:	Reaction rate constant Chemistry Analytical chemistry General Physics and Astronomy Thermodynamics Inverse temperature Physical and Theoretical Chemistry Atmospheric temperature range Mass spectrometric
Zdroj:	Chemical Physics Letters. 439:3-7
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2007.03.032
Popis:	The rate constant of the F + NH 3 reaction has been determined in the temperature range 276–327 K, using a discharge-flow mass spectrometric technique. A relative rate method has been employed, using the F + CH 4 reaction as a reference reaction. The rate of the F + NH 3 reaction was found to increase significantly as the temperature is lowered. The present results are compared with previous published experimental and theoretical results. The inverse temperature dependence reported in this study is significantly stronger than what has been reported until now for any other reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::765bdb863499bbc851780e0080b69c7f https://doi.org/10.1016/j.cplett.2007.03.032 Zobrazit plný text záznamu Full Text from ScienceDirect