Synthesis and carbene dissociation of functionally substituted diazoacetic acid esters. Communication 3. Synthesis of 2-aminoethyldiazoacetates and N-(2-hydroxyethyl)-N-alkyldiazoacetamides by reaction of 2-bromoethyldiazoacetate with aliphatic amines

Autor:	Oleg M. Nefedov, T. A. Bunkina, I. E. Dolgii, T. N. Romanova, E. A. Shapiro
Rok vydání:	1987
Předmět:	chemistry.chemical_compound Chemistry Anhydrous Organic chemistry Amine gas treating General Chemistry Acetonitrile Carbene Dissociation (chemistry)
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:1240-1243
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00956670
Popis:	1. Reaction of 2-bromoethyldiazoacetate with free secondary amines or primary amine chlorohydrates in the presence of anhydrous K2CO3 in acetonitrile at 20°C affords the correponding aminoethyldiazoacetates in a yield of up to 80%. 2. Reaction of 2-bromoethyldiazoacetate with free primary amines in the presence of K2CO3 is accompanied by ammonolysis of the diazoester and affords previously unknown N-alkyl-N-(2-hydroxyethyl)diazoacetamides in yields of up to 70%.
Databáze:	OpenAIRE
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