Influence of Media on Processes of Radiation-Induced Polymerization of White Phosphorus

Autor:	I.M. Artemkina, Natalia Tarasova, Yu. V. Smetannikov, A. S. Vilesov
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Order of reaction White Phosphorus Organic Chemistry Inorganic chemistry Solution polymerization Polymer Biochemistry Inorganic Chemistry Reaction rate chemistry.chemical_compound Reaction rate constant chemistry Polymerization Ionic liquid
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 183:586-593
ISSN:	1563-5325 1042-6507
Popis:	Radiation-induced polymerization of elemental phosphorus in the presence of ionic liquids(IL) was investigated. Composition, structure, and properties of the products-phosphorus-containing polymers (PCPs)-were examined by the methods of physicochemical analysis. It was found that the structure of ionic liquid and its concentration in the media has a significant influence on the polymerization rate. Some kinetic properties of the radiation-induced polymerization process of the elemental phosphorus in the presence of ionic liquids in the mixed solvent “dimethylsulfate (DMSO)/benzene” were determined (reaction rate, effective rate constant, reaction orders).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::75eaf0b8f4e766830a1a3f4ef7cdc57e https://doi.org/10.1080/10426500701765004 Zobrazit plný text záznamu