The functionalization of saturated hydrocarbons. Part XIX. Oxidation of alkanes by H2O2 in pyridine catalyzed by copper(II) Complexes. A Gif-Type Reaction

Autor:	Derck H.R. Barton, Dario Doller, Yurii V. Geletti, Eva Csuhai
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Cyclododecane Chemistry Organic Chemistry chemistry.chemical_element Biochemistry Copper Catalysis chemistry.chemical_compound Hydrocarbon Polycyclic compound Drug Discovery Polymer chemistry Pyridine Organic chemistry Aliphatic compound Hydrogen peroxide
Zdroj:	Tetrahedron. 47:6561-6570
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)82310-3
Popis:	The Cu II -catalyzed oxidation of saturated hydrocarbons by hydrogen peroxide proceeds in pyridine-acetic acid solutions affording mainly ketones as the reaction product. The conversion of hydrocarbon is about 20–30 %. This system (called GoChAgg) shares with the Fe III -catalyzed system (GoAgg II ) its unusual chemical characteristics.
Databáze:	OpenAIRE
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