Comparison of hybrid ultrafiltration-osmotic membrane bioreactor and conventional membrane bioreactor for oil refinery effluent treatment

Autor: Clara V. Faria, Ana Cláudia Cerqueira, Bárbara C. Ricci, Eduardo Coutinho de Paula, Míriam Cristina Santos Amaral, Priscila Barbosa Moser, Clara Bretas
Rok vydání: 2019
Předmět:
Zdroj: Chemical Engineering Journal. 378:121952
ISSN: 1385-8947
DOI: 10.1016/j.cej.2019.121952
Popis: Although membrane bioreactors (MBR) has become the preferred choice for oil refinery reclamation, the osmotic membrane bioreactor (OMBR) has gained interest in the last years because of the low membrane fouling propensity and the high rejection capacity to both inorganic and organic contaminants. However, progress of OMBR is hindered by the salinity build-up in the bioreactor. This study evaluated the hybrid ultrafiltration-osmotic membrane bioreactors (UF-OMBR) performance in the treatment of oil refinery effluent and compare its performance with conventional MBR focusing the mixed liquor characteristics, the membrane fouling and the overall performance. The results indicated that the salinity build-up in the biological reactor was successfully prevented by integrating ultrafiltration to OMBR. Dissolved organic carbon (DOC) removal efficiencies for the UF and FO in the UF-OMBR were 81 ± 15 and 99.6 ± 0.5%, respectively, while for UF in the conventional MBR was 66 ± 8%. The high removal efficiency for UF in UF-OMBR compared to UF in conventional MBR can be attributed to the longer retention time of recalcitrant organic compounds. This could occur due to the high rejection of FO membrane which is not attenuated by UF permeate as efficiently as it was observed for salinity. However, this organic matter build-up in the biological reactor contributed to the greater UF membrane fouling in UF-OMBR compared to in conventional MBR. Low fouling tendency was observed for FO membrane. Overall, the UF-OMBR process was able of simultaneously producing two streams (UF and FO permeate) with different opportunities for water reclamation.
Databáze: OpenAIRE