Magneto-optical spectra and electron structure of Nd 0.5 Gd 0.5 Fe 3 (BO 3 ) 4 single crystal
Autor: | V. L. Temerov, A. L. Sukhachev, V. G. Piryatinskaya, S. L. Gnatchenko, A.V. Malakhovskii, I. S. Kachur |
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Rok vydání: | 2016 |
Předmět: |
Materials science
Absorption spectroscopy Magnetic circular dichroism Landé g-factor 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Electronic Optical and Magnetic Materials Ion Crystal Paramagnetism 0103 physical sciences Atom Atomic physics 010306 general physics 0210 nano-technology Single crystal |
Zdroj: | Journal of Magnetism and Magnetic Materials. 401:517-524 |
ISSN: | 0304-8853 |
DOI: | 10.1016/j.jmmm.2015.10.074 |
Popis: | Polarized absorption spectra and magnetic circular dichroism (MCD) spectra of Nd 0.5 Gd 0.5 Fe 3 (BO 3 ) 4 single crystal were measured in the range of 10000–21000 cm −1 and at temperatures 2–300 K. On the basis of these data, in the paramagnetic state of the crystal, the 4 f states of the Nd 3+ ion were identified in terms of the irreducible representations and in terms of | J , ± M J 〉 wave functions of the free atom. The changes of the Lande factor during f–f transitions were found theoretically in the | J , ± M J 〉 wave functions approximation and were determined experimentally with the help of the measured MCD spectra. In the majority of cases the experimentally found values are close to the theoretically predicted ones. |
Databáze: | OpenAIRE |
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