Solvation of excess electrons in apolar solvents

Autor:	E. E. Kunhardt, S. Petrucci
Rok vydání:	1991
Předmět:	Electron mobility Chemistry General Engineering Solvation Activation energy Electron Induced polarization Condensed Matter::Soft Condensed Matter Solvent Stability constants of complexes Chemical physics Physics::Chemical Physics Physical and Theoretical Chemistry Atomic physics
Zdroj:	The Journal of Physical Chemistry. 95:5605-5610
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100167a044
Popis:	Statistical thermodynamic theories for the solvation of excess electrons in apolar solvents, in particular, straight-chain hydrocarbons are developed. Relations between activation energies for drift mobility and solvent properties are found by using a quasi-chemical approach. The Bjerrum-like method calculates the «chemical» formation constant of an excess electron-solvent species formed under the influence of the induced polarization energy (due to the presence of the excess electron). A simplified model based on the induced potential of a tetrahedral polarized solvent trap surrounding the electron is also discussed. This second method also yields values of the activation energies for drift mobility of excess electrons in straight-chain hydrocarbons
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::757b5a6cdf8539a88f48fdea92a6cb54 https://doi.org/10.1021/j100167a044 Zobrazit plný text záznamu