[Me4N]3[(WOS3)2Ag]·MeCN – An Acetonitrile Solvate with Linear Complex Anions

Autor:	R. Dilshad, Kurt O. Klepp, H. Boller
Rok vydání:	2006
Předmět:	Crystallography chemistry.chemical_compound Chemistry Molecule General Chemistry Crystal structure Acetonitrile Single crystal Layer (electronics) Ion Diffractometer
Zdroj:	Zeitschrift für Naturforschung B. 61:867-870
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2006-0715
Popis:	The title compound was prepared by the reaction of [Me4N]2WOS3 with AgCN in MeCN at room temperature and slow crystallisation in the refrigerator. It was characterized by IR and mass spectroscopy. It crystallizes in the orthorhombic space group Pnma (No. 62) with unit cell dimensions a = 19.648(7), b = 27.878(12), c = 11.494(3) Å , Z = 8. The crystal structure was determined from single crystal diffractometer data (Mo-Kα radiation) and refined to R = 0.077. The structure is composed of mixed double layers containing the linear trinuclear anion [(WOS3)2Ag]3− and cations separated by a layer formed by cations and solvating acetonitrile molecules.
Databáze:	OpenAIRE
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