Spectrum analysis of U3+:LaCl3
| Autor: | A. P. Paszek, H. M. Crosswhite, W. T. Carnall |
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| Rok vydání: | 1980 |
| Předmět: | |
| Zdroj: | The Journal of Chemical Physics. 72:5103-5117 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.439742 |
| Popis: | The spectrum of U3+:LaCl3 has been analyzed; 53 crystal states of electronic origin have been identified, many of them accompanied by extensive vibronic sidebands having a recognizable structure similar to that for lanthanide‐doped LaCl3. Seventeen energy level parameters were varied simultaneously in a least‐squares adjustment yielding a mean error of 26 cm−1. Values for the crystal field parameters are: B20=260±64 cm−1, B40=−532±139 cm−1, B60=−1438±113 cm−1 and B66=1025±88 cm−1. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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