The base-catalysed equilibration of 6α-Nitrocholest-4-ene and 6β-Nitrocholest-4-ene

Autor:	GC Smith, JT Pinhey
Rok vydání:	1978
Předmět:	Green chemistry chemistry.chemical_classification Reaction mechanism Base (chemistry) General Chemistry Medicinal chemistry Sodium methoxide Catalysis chemistry.chemical_compound chemistry Biocatalysis Organic chemistry Methanol Ene reaction
Zdroj:	Australian Journal of Chemistry. 31:2563
ISSN:	0004-9425
DOI:	10.1071/ch9782563
Popis:	Treatment of 6β-nitrocholest-4-ene with a catalytic amount of sodium methoxide in methanol gave an equilibrium mixture which contained the starting material and the 6α-epimer in a 1 : 1 ratio. The unusual stability of the 6β-epimer is explained by electronic factors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7570a44b7007465b1d29bc3f870261a5 https://doi.org/10.1071/ch9782563 Zobrazit plný text záznamu