Structure of chloro[1,1,1-tris(diphenylphosphinomethyl)ethane]copper(I)
Autor: | D. J. Fife, C. F. Campana, H. J. Mueh |
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Rok vydání: | 1993 |
Předmět: | |
Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 49:1714-1716 |
ISSN: | 0108-2701 |
DOI: | 10.1107/s0108270193006584 |
Popis: | [CuCl(C 41 H 39 P 3 )], M r = 723.6, orthorhombic, Pna2 1 , a=20.704 (16), b=10.287 (6), c=16.982 (8) A, V=3617 (4) A 3 , Z=4, D x = 1.329 g cm -3 , λ(Mo Kα)=0.71073 A, μ=8.37 cm -1 , F(000)=1504, T=296 K, R=0.050 for 1754 independent observed reflections with I>2.0σ(I). The copper(I) complex, Cu(p 3 )Cl, of the tridentate ligand 1,1,1-tris(diphenylphosphinomethyl)ethane, [(C 6 H 5 ) 2 PCH 2 ] 3 CCH 3 (p 3 ), has been prepared and characterized by complete X-ray cyrstal structure analysis |
Databáze: | OpenAIRE |
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