Chemical Transformations of Tetracyclo[3.3.1.1.3,7.0.1,3]decane (1,3-Dehydroadamantane): VIII. Reaction of 1,3-Dehydroadamantane with Aliphatic Aldehydes

Autor:	V. M. Mokhov, K. R. Saad, Gennady M. Butov, G. Yu. Parshin
Rok vydání:	2019
Předmět:	chemistry.chemical_compound chemistry 010405 organic chemistry Yield (chemistry) Organic Chemistry Organic chemistry One stage 1 3-Dehydroadamantane Decane 01 natural sciences 0104 chemical sciences
Zdroj:	Russian Journal of Organic Chemistry. 55:640-645
ISSN:	1608-3393 1070-4280
DOI:	10.1134/s1070428019050099
Popis:	The reaction of 1,3-dehydroadamantane with aliphatic aldehydes involves the Ca-H bond and forms hardly accessible branched 2-(1-adamantyl)alkylaldehydes in one stage in a yield of 60-78%. It is found that 2-(1-adamantyl)alkylaldehydes are prone to oligomerization. The reaction of 2-(1-adamantyl)-alkylaldehydes with 2,4-dinitrophenylhydrazine gave the corresponding hydrazones in a yield of 84-98%.
Databáze:	OpenAIRE
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