Synthesis of Stereoselectively Functionalized Silacyclopentanes

Autor:	Yuki Yamanaka, Akihiro Kuroo, Daisuke Yoshihiro, Kazunobu Igawa, Katsuhiko Tomooka
Rok vydání:	2017
Předmět:	Tsuji–Trost reaction Stereospecificity 010405 organic chemistry Chemistry Organic Chemistry Enantioselective synthesis Organic chemistry Mitsunobu reaction 010402 general chemistry 01 natural sciences 0104 chemical sciences Stereocenter
Zdroj:	Synlett. 28:2445-2448
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0036-1590826
Popis:	An efficient approach to a variety of chiral silacyclopentanes having silicon stereogenic center based on the stereospecific transformations of C4 carbon stereogenic center of silacyclopentenols by ­Mitsunobu reaction or Tsuji–Trost reaction has been developed. The thus obtained substitution products can be converted into novel silacyclopentane triols, amines, and carboxylic acids in stereospecific manner.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::753af0feec3bb1a5ebbbb957835945d0 https://doi.org/10.1055/s-0036-1590826 Zobrazit plný text záznamu