New Type of Polymeric Chain Constructed by Exo-bidentate Binaphthol Derivative

Autor:	Ben-Lai Wu, Yaqiong Gong, Rui-Hua Wang, Ben-Yong Lou, Lei Han, Maochun Hong
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Denticity Ligand Coordination polymer General Chemistry Crystal structure Polymer Triclinic crystal system chemistry.chemical_compound Crystallography chemistry Polymer chemistry Single crystal Derivative (chemistry)
Zdroj:	Chinese Journal of Chemistry. 23:1367-1370
ISSN:	1614-7065 1001-604X
Popis:	The self-assembly of a racemic exo-bidentate ligand 2,2′-bis(4-pyridylmethyloxy)-1,1′-binaphthyl, namely Rac-L, with cadmium(II) salt gave rise to a new one-dimensional polymer, which has been characterized by single crystal X-ray diffraction analysis. The polymer crystallizes in a triclinic space group P-1 with unit cell parameters: a=0.6976(1) nm, b=1.30160(14) nm, c=1.71146(17) nm,α=105.141(3) °,β=94.263(5)°,γ=100.405(4)°, V=1.4633(2) nm3, Z=2, C32H29CdCl2N2O4.5, M=696.88, Dc=1.584 g/cm3, F(000) =708, μ(Mo Kα) =0.972 mm−1. The final R and wR are 0.0498 and 0.1282 for 5079 observed reflections with I≥δ(I).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::751a0bda35aa072e4f94ace35c5b3fce https://doi.org/10.1002/cjoc.200591367 Zobrazit plný text záznamu Plný text