Role of the ancillary ligand in controlling the lysozyme affinity and electronic properties of terpyridine fac-Re(CO)3 complexes

Autor:	Ola R. Shehab, Ahmed M. Mansour, Krzysztof Radacki
Rok vydání:	2021
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Solvatochromism Click chemistry Terpyridine Lysozyme Ligand (biochemistry) Medicinal chemistry Cycloaddition Electronic properties Adduct
Zdroj:	Dalton Transactions. 50:1197-1201
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt04140h
Popis:	The lysozyme binding affinity and the electronic properties of [ReX(CO)3(terpy-κ2N1,N2)] (X = Br− and triazolateCOOCH2CH3,CF3) were reported. The triazolate complex was prepared in a [3 + 2] cycloaddition click reaction. The bromo compound reacted with lysozyme affording adducts with Re(CO)3+ fragments, while the triazolate compound persisted. A red shift of the MLCT band of the triazolate compound in progressively less polar solvents may be due to the negative solvatochromism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7506e8543472031ff052a6fb17bbd9ba https://doi.org/10.1039/d0dt04140h Zobrazit plný text záznamu