ChemInform Abstract: Synthesis of Benzo[a]carbazole Derivatives from 3-Ethylindoles by Exploiting the Dual Character of Benzoquinone as an Oxidizing Agent and Dienophile
Autor: | Lyu Lin, Chia Yu Huang, Ting Ta Chiang, Tang Hao Yang, Ching Fa Yao, Ashok Konala, Chun Wei Kuo, Veerababurao Kavala |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | ChemInform. 47 |
ISSN: | 0931-7597 |
DOI: | 10.1002/chin.201644112 |
Popis: | The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is generated in situ from the 3-ethylindole derivative with the help of benzoquinone, where it acts as an oxidizing agent. Later it serves as a dienophile and participates in a Diels–Alder reaction with the diene to afford benzo[a]carbazole derivatives. |
Databáze: | OpenAIRE |
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