Autor: | Hiroko Seki, Tsutomu Ishikawa, Tatsuhiro Tokunaga, Masahiro Suzukawa, Keiro Higuchi, Hiroyo Kabasawa, Keiko Yanagisawa, Masako Ikeno |
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Rok vydání: | 2002 |
Předmět: |
Nitrosourea
Organic Chemistry Inorganic chemistry Oxidative phosphorylation Oxygenation Biochemistry Medicinal chemistry Catalysis Nitric oxide Inorganic Chemistry chemistry.chemical_compound chemistry Drug Discovery Nitrosation Urea Urea derivatives Physical and Theoretical Chemistry Derivative (chemistry) |
Zdroj: | Helvetica Chimica Acta. 85:2636-2643 |
ISSN: | 1522-2675 0018-019X |
DOI: | 10.1002/1522-2675(200209)85:9<2636::aid-hlca2636>3.0.co;2-l |
Popis: | The chemistry of N-hydroxyguanidines, focusing on photo-sensitized oxygenation and reaction with nitric oxide (NO), was examined. In the former reaction, a urea derivative was obtained as the main product together with the generation of NO. On the other hand, in the latter case, oxidative nitrosation occurred under aerobic conditions to give a nitrosourea derivative, which was also obtained from urea by the same treatment. |
Databáze: | OpenAIRE |
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