The crystal structure of (23R, 25S)-3β-bromo-6β-acetoxy-5α-spirostan-23-ol monohydrate

Autor:	R. Perez Gil, R. Pomés Hernández, R. C. Peterson, M. A. Iglesias Arteagas, O. Au-Alvarez, F. Coll Manchado
Rok vydání:	2000
Předmět:	Inorganic Chemistry Crystal Hydrogen bond Stereochemistry Group (periodic table) Chemistry Moiety Molecule General Materials Science Crystal structure Condensed Matter Physics Ring (chemistry) Monoclinic crystal system
Zdroj:	Zeitschrift für Kristallographie - Crystalline Materials. 215:179-181
ISSN:	2196-7105 2194-4946
DOI:	10.1524/zkri.2000.215.3.179
Popis:	The structure of the title compound, C29H47BrO6, has been determined by direct methods. The crystal is monoclinic, space group P21 with a = 16.404(5) Å, b = 7.135(5) Å, c = 12.536(5) Å, β = 103.32(3)° and Z = 2. The structure presents a hydrogen bond between the H2O molecule and the 23-hydroxyl group of the spirostan moiety. All ring junctions are trans and the molecule is twisted to only a small extent about the length of the spirostan moiety. The C=O distance of the acetate group is smaller than expected.
Databáze:	OpenAIRE
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