Solid-State 45Sc NMR Studies of Cp*2Sc–OR (R = CMe2CF3, CMe(CF3)2, C(CF3)3, SiPh3) and Relationship to the Structure of Cp*2Sc-Sites Supported on Partially Dehydroxylated Silica
| Autor: | Matthew P. Conley, Damien B. Culver, Hosein Tafazolian, Winn Huynh |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Organic Chemistry Solid-state Nuclear magnetic resonance spectroscopy 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Coupling (electronics) chemistry.chemical_compound Crystallography chemistry Alkoxide Quadrupole Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 39:1112-1122 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | Cp*2Sc–OR (R = CMe2CF3, CMe(CF3)2, C(CF3)3, SiPh3) was synthesized to determine how the alkoxide affects the quadrupole coupling (CQ) obtained from solid-state 45Sc{1H} NMR spectroscopy. These alko... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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