Crystal Structure and Luminescence of the [DyCl2(H2O)6]Cl Complex

Autor: B. V. Bukvetskii, A. G. Mirochnik, P. A. Zhikhareva
Rok vydání: 2020
Předmět:
Zdroj: Optics and Spectroscopy. 128:323-326
ISSN: 1562-6911
0030-400X
DOI: 10.1134/s0030400x20030054
Popis: The crystal structure of the [DyCl2(H2O)6]Cl complex is studied by X-ray diffraction analysis. The crystals are constructed of complex cations [DyCl2(H2O)6]+ and outer-sphere Cl−1 ions. The structure is represented by separate [DyCl2(H2O)6] complexes bound by a dense network of $${\text{O}{-}\text{H}}\cdots{\text{Cl}}$$ hydrogen bonds. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a weakly distorted square antiprism. The results of investigation of the luminescent properties of the complex are presented.
Databáze: OpenAIRE
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