Dielectric Properties of Tungsten Copper Barium Ceramic as Promising Colossal-Permittivity Material

Autor: Guangzhao Li, Lajun Feng, Xiaolian Chao, Juanjuan Wang, Tiantian Ning, Kang Zhao
Rok vydání: 2017
Předmět:
Zdroj: Journal of Electronic Materials. 46:4697-4700
ISSN: 1543-186X
0361-5235
DOI: 10.1007/s11664-017-5504-y
Popis: Ba(Cu0.5W0.5)O3 (BCW) ceramic has been fabricated and its dielectric properties investigated for use in energy-storage applications, revealing a very large dielectric constant (∼104) at 1 kHz. Moreover, the colossal-permittivity BCW ceramic exhibited fine microstructure and optimal temperature stability over a wide temperature range from room temperature to 500°C. The internal barrier layer capacitor mechanism was considered to be responsible for its high dielectric properties. Based on activation values, it is concluded that doubly ionized oxygen vacancies make a substantial contribution to the conduction and relaxation behaviors at grain boundaries. This study suggests that this kind of material has potential for use in high-density energy storage applications.
Databáze: OpenAIRE