cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(v)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

Autor:	Kotohiro Nomura, Sapanna Chaimongkolkunasin
Rok vydání:	2020
Předmět:	Polymer yield chemistry.chemical_compound chemistry Polymer chemistry Ring-opening metathesis polymerisation Cycloheptene Vanadium chemistry.chemical_element ROMP Cyclic Olefins Catalysis Norbornene
Zdroj:	Catalysis Science & Technology. 10:5840-5846
ISSN:	2044-4761 2044-4753
Popis:	Highly cis-specific (Z selective) ring opening metathesis polymerisation of cycloheptene (CHPE) as well as norbornene has been demonstrated using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2; the molecular weight of poly(CHPE) increased with increasing polymer yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::74a75179853c077dea64f49c46bfb1b7 https://doi.org/10.1039/d0cy00938e Zobrazit plný text záznamu