ChemInform Abstract: A Simple and Efficient Procedure for Diazotization-Iodination of Aromatic Amines in Aqueous Pastes by the Action of Sodium Nitrite and Sodium Hydrogen Sulfate

Autor:	A. N. Tret'yakov, Ki-Whan Chi, Dmitry A. Gorlushko, Eun Hye Cha, N. I. Semenishcheva, Elena A. Krasnokutskaya, Bong Seong Go, Victor D. Filimonov, Ho Yun Hwang
Rok vydání:	2009
Předmět:	chemistry.chemical_compound Aqueous solution chemistry Hydrogen Sulfate Sodium chemistry.chemical_element Halogenation Organic chemistry Diiodomethane General Medicine Sodium nitrite Alkyl nitrites Iodine
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200919064
Popis:	One of the most widely used methods of synthesis of aromatic iodides is based on diazotization–iodina-tion of aromatic amines. The diazotization is generally carried out using accessible sodium nitrite in strongly acidic medium at reduced temperature [1–5]. Alter-native procedures involve more expensive alkyl nitrites as diazotizing agents in the presence of diiodomethane or other sources of iodine [6, 7]. We previously pro-posed simple procedures for diazotization–iodination with sodium nitrite at room temperature in weakly acidic media created by
Databáze:	OpenAIRE
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