ChemInform Abstract: Hexanes/Acetonitrile: A Binary Solvent System for the Efficient Monosilylation of Symmetric Primary and Secondary Diols

Autor:	Burkhardt I. Wilke, Jon Yeung, Mark H. Dornan, Atahualpa Pinto, Christopher N. Boddy
Rok vydání:	2014
Předmět:	Solvent system Primary (chemistry) integumentary system organic chemicals Binary number General Medicine chemistry.chemical_compound chemistry polycyclic compounds Organic chemistry heterocyclic compounds Solubility Acetonitrile hormones hormone substitutes and hormone antagonists
Zdroj:	ChemInform. 45
ISSN:	0931-7597
Popis:	Symmetric diols are useful compounds in the synthesis of natural products, their value often dependent on their successful monoprotection. A general and simple method for the monosilylation of symmetrical primary and secondary diols is reported. The method exploits the solubility differential of diols and their monosilylated counterparts in a binary hexanes/acetonitrile solvent system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::746e6ecc095bff5263b522f782fe678b https://doi.org/10.1002/chin.201440190 Zobrazit plný text záznamu Plný text