ChemInform Abstract: Chemo- and Regioselective Reductive Deoxygenation of 1-En-4-yn-ols into 1,4-Enynes Through FeF3and TfOH Co-Catalysis

Autor:	Zonglian Yang, Rapolu Kiran Kumar, Xihe Bi, Xingqi Li, Zhaohong Liu, Peiqiu Liao
Rok vydání:	2016
Předmět:	Chemistry Regioselectivity Organic chemistry General Medicine Deoxygenation Catalysis
Zdroj:	ChemInform. 47
ISSN:	0931-7597
Popis:	We report chemo- and regioselective direct reductive deoxygenation of 1-en-4-yn-3-ols into 1,4-enynes through FeF3 and TfOH cooperative catalysis under NBSH-mediated conditions. Further, we show the efficient synthesis of a pharmaceutically significant 1,4-enyne. The present methodology can also be used for chemo- and regioselective direct deoxygenation of other alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::74600d39f33d1ba99f77c1fdc2f1bf21 https://doi.org/10.1002/chin.201635037 Zobrazit plný text záznamu Plný text