NMR spectroscopic and polarographic studies of the reaction of decomposition of cumene hydroperoxide by dithiophosphoric acids

Autor:	P. A. Kirpichnikov, G. Komber, G. Grossman, D. G. Pobedimskii, G. Kroshvitts, N. A. Mukmeneva
Rok vydání:	1989
Předmět:	inorganic chemicals Polarography chemistry.chemical_compound Chemistry Cumene hydroperoxide Inorganic chemistry Organic chemistry Sulfuric acid General Chemistry Decomposition Catalysis
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 38:26-32
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00953693
Popis:	1. Dithiophosphoric acids are either not catalysts or only act as moderate catalysts as a function of the structure in reactions of decomposition of CHP. 2. The real catalyst of decomposition of CHP in the presence of dithiophosphoric acids is the sulfuric acid formed during the oxidation of the dithiophosphoric acids, or the combination of the sulfuric acid with phosphours-containing acids. 3. Slow and fast stages of kinetic decomposition of CHP were detected, and the kinetic parameters of the fast stage were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7457a5cfd15a488db7b88b71a60b4cba https://doi.org/10.1007/bf00953693 Zobrazit plný text záznamu Full text from SpringerLink