Studies in group iv organometallic chemistry. XX: Addition of Trialkyltin Hydrides to Substituted Acetylenes: The Structure of the Addition Products

Autor:	J.W. Marsman, A.J. Leusink, H.A. Budding
Rok vydání:	1965
Předmět:	chemistry.chemical_compound Group (periodic table) Chemistry Organic chemistry General Chemistry Nuclear magnetic resonance spectroscopy Triple bond Medicinal chemistry Organometallic chemistry Adduct
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 84:689-703
ISSN:	0165-0513
DOI:	10.1002/recl.19650840604
Popis:	The addition of trialkyltin hydrides to mono- and di-substituted acetylenes has been studied more closely. The identity and geometry of the resulting 1:1 adducts have been established by means of GLC, IR and NMR spectroscopy, elementary analysis and degradation reactions. Both terminal and non-terminal addition of the trialkylstannyl group has been observed. Trans-addition of the Sn-H bond across the triple bond seems to occur mainly.
Databáze:	OpenAIRE
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