Structure of 1,1-dicarbonyl-1,1-bis(dimethylphenylphosphine)-2,3-bis(methoxycarbonyl)-1-ruthenaindene, a ruthenium(II) complex containing a five-membered metallacycle
| Autor: | J. R. Crook, A. J. Reid, C. D. Reynolds, F. Giordano, Roger J. Mawby |
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| Rok vydání: | 1990 |
| Předmět: |
chemistry.chemical_classification
Bicyclic molecule Stereochemistry Dimethylphenylphosphine chemistry.chemical_element General Medicine Crystal structure Metallacycle General Biochemistry Genetics and Molecular Biology Ruthenium chemistry.chemical_compound chemistry X-ray crystallography Molecule Inorganic compound |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 46:41-44 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270189005597 |
| Popis: | [Ru(C 12 H 10 O 4 )(C 8 H 11 P) 2 (CO) 2 ] cristallise dans P1 avec a=11,858, b=11,958 et c=12,970 A, α=99,41, β=82,42 et γ=60,93 o , Z=2; affinement jusqu'a R=0,044. A l'etat solide, le complexe existe sous forme d'unites monomeres discretes avec un octaedre legerement irregulier autour de Ru |
| Databáze: | OpenAIRE |
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