Aggregation behavior of polystyrene-based amphiphilic diblock copolymers in organic media

Autor:	Yosuke Watanabe, Makoto Masaoka, Akihito Hashidzume, Tomoe Arai, Takahiro Sato, Tomohiro Michitaka
Rok vydání:	2013
Předmět:	Polymers and Plastics Radical polymerization Chain transfer Chloride Micelle chemistry.chemical_compound Polymerization chemistry Amphiphile Polymer chemistry Materials Chemistry Copolymer medicine Polystyrene medicine.drug
Zdroj:	Polymer Journal. 46:189-194
ISSN:	1349-0540 0032-3896
DOI:	10.1038/pj.2013.80
Popis:	Two polystyrene-based amphiphilic diblock copolymers, PS(x)-PV(y) and PS(x)-PA(y) (where PS(x)-PV(y) and PS(x)-PA(y) possess poly[(ar-vinylbenzyl)trimethylammonium chloride] and poly(2-acrylamido-2-methylpropanesulfonic acid) blocks, respectively, and x and y are the degrees of polymerization), were prepared by reversible addition-fragmentation chain transfer radical polymerization to investigate their formation of reverse micelles in less polar organic media. Theoretical analysis using light scattering data indicated that PS(x)-PV(y) formed star-like micelles at x/y>6 and brush-like micelle micelles at x/y
Databáze:	OpenAIRE
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