IR Manifestation of Non-Covalent Interaction in Organic Liquids
| Autor: | Anton N. Petukhov, R. V. Kapustin, I. I. Grinvald, I. Yu. Kalagaev |
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| Rok vydání: | 2019 |
| Předmět: |
Condensed Matter::Quantum Gases
Hydrogen bond Infrared spectroscopy 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Atom Cluster (physics) Molecule Physics::Atomic Physics Physics::Chemical Physics Physical and Theoretical Chemistry 0210 nano-technology Acetonitrile Benzene Methyl iodide |
| Zdroj: | Russian Journal of Physical Chemistry A. 93:2645-2649 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s0036024419130107 |
| Popis: | In this paper the IR manifestation of non-covalent interactions in benzene, methyl iodide and acetonitrile is considered. It was shown that the molecules of the mentioned compounds can form cluster shapes not only in condensed state, but also in gas phase. These structures appear due to the hydrogen bond or owing to the interaction between negatively charged atom (iodine atom) or fragment (CN-group) with a carbon atom of a neighboring molecule. As a result, the molecular chains arise, leading to the high stability of condensed state along with the dipole-dipole interaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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