A rational step-by-step preparation of a chlorin from linear tetrapyrroles

Autor: M. W. Burden, Dennis H. Burns, Tim M. Caldwell
Rok vydání: 1993
Předmět:
Zdroj: Tetrahedron Letters. 34:2883-2886
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)60471-9
Popis: Formation of porphodimethene 2 by condensation of pyrromethanes 3 and 4 , metalation with Zn(OAc) 2 under neutral conditions and heating to 55°C for 1 hour in chloroform produces chlorin 5 in 27% yield.
Databáze: OpenAIRE