Behavior of N-alkoxybenzimidzoles with respect to nucleophilic reagents. Attempts to synthesize N-hydroxy-2-aminobenzimidazoles

Autor:	M. M. Medvedeva, V. V. Bessonov, V. V. Kuz'menko, Alexander F. Pozharskii, B. A. Tertov
Rok vydání:	1979
Předmět:	chemistry.chemical_compound Benzimidazole chemistry Nucleophile Amide Reagent Sodium amide Organic Chemistry Alkoxy group Benzophenone Organic chemistry Group 2 organometallic chemistry
Zdroj:	Chemistry of Heterocyclic Compounds. 15:166-172
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00480362
Popis:	Various possibilities for the synthesis of N-hydroxy- and N-alkoxy derivatives of 2-aminobenzimidazoles — reductive cyclization of o-nitrophenylureas, the action of sodium amide on 1-alkoxybenzimidazoles, the ammonolysis of 1-alkoxy-2-iodobenzimidazoles, etc. — were investigated. Organometallic compounds of 1-alkoxybenzimidazoles were obtained for the first time, and their reactivities with respect to benzophenone, iodine, and 1-substituted benzimidazoles were studied. 2,2′-Dibenzimidazolyls that contain an alkoxy group in the 1 position were synthesized.
Databáze:	OpenAIRE
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