Liquid-phase Oxidation Catalyzed by Cu(II)–Cl. III. Oxidation of 1,2,3,4-Tetrahydronaphthalene

Autor:	Seiichiro Imamura, Hiroshi Teranishi, Hideki Aomi, Takao Sumi, Yoshinobu Takegami, Masaaki Teramoto
Rok vydání:	1976
Předmět:	Dimer Inorganic chemistry chemistry.chemical_element General Chemistry Copper Chloride Decomposition Ion Catalysis Acetic acid chemistry.chemical_compound chemistry Polymer chemistry medicine Lithium chloride medicine.drug
Zdroj:	Bulletin of the Chemical Society of Japan. 49:1659-1665
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.49.1659
Popis:	1,2,3,4-Tetrahydronaphthalene was oxidized in the presence of copper(II) acetate in glacial acetic acid. An addition of lithium chloride which formed complexes with copper(II) ion highly accelerated the reaction, and the initiating process was found to be the decomposition of 1,2,3,4-tetrahydro-1-naphthyl hydroperoxide by the copper(II)–chloride ion complexes. However, only about 8% of the decomposition contributed the initiation, and it was suggested that the larger part of the decomposition proceeded through a non-ionic mechanism. Spectrophotometric and ESR experiments suggested that one of the accelerating effects of the chloride ion was due to its action to decompose the inactive copper(II) acetate dimer and form active copper(II)–chloride ion complexes and that the order of the activity of the complexes was CuCl+
Databáze:	OpenAIRE
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