A structural model for oxidized type II copper nitrite reductase with a polyimidazole tripodal ligand

Autor:	Marciela Scarpellini, Eduardo Fausto de Almeida Neves, Eduardo E. Castellano, Douglas Wagner Franco, Ademir Neves
Rok vydání:	2004
Předmět:	Ligand Inorganic chemistry chemistry.chemical_element Crystal structure Copper Square pyramidal molecular geometry Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Tripodal ligand Materials Chemistry Imidazole Physical and Theoretical Chemistry Nitrite Cyclic voltammetry
Zdroj:	Polyhedron. 23:511-518
ISSN:	0277-5387
Popis:	The new copper(II)–nitrite complex [CuII(L)(ONO)]ClO4 (2), L=[(bis(1-methylimidazol-2-yl)methyl)(2-(pyridyl-2-yl)ethyl)amine] was synthesized and characterized by cyclic voltammetry, UV–Vis spectroscopy, X-band EPR and X-ray crystallography. Complex 2 crystallizes in the monoclinic system, space group P21/n and has the metal center in a somewhat distorted square pyramidal geometry, with three nitrogen atoms from the chelate ligand and one nitrite ion outlining the basal plane. One imidazole nitrogen from the tripodal molecule is at the apical position at 2.158(2) A from the metal. Spectrophotometric and electrochemical experiments in water solution reveal that complex 2 readily releases the nitrite ligand in this medium (t1/2
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::73bebdd6bb2c1753b0cca3f630e88759 https://doi.org/10.1016/j.poly.2003.09.036 Zobrazit plný text záznamu Full Text from ScienceDirect