Structure of Diamond-Like Silicon–Carbon Films Alloyed by Vanadium

Autor: M. L. Shupegin, O. M. Zhigalina, I. G. Dyachkova, D. N. Khmelenin, V. E. Asadchikov, S. M. Pimenov
Rok vydání: 2018
Předmět:
Zdroj: Crystallography Reports. 63:796-801
ISSN: 1562-689X
1063-7745
DOI: 10.1134/s1063774518050334
Popis: The structure of diamond-like silicon–carbon films formed on silicon substrates by magnetron and plasmatron codeposition using a closed-field magnetron and a plasmatron activated by tungsten cathode has been studied by transmission electron microscopy. The main feature of the films alloyed by vanadium to concentrations of 12–31 at % was found to be a layered structure of the film cross section. It was established that vanadium alloying leads to the formation of vanadium carbide (VC) nanocrystals; the nanocrystal size increases from 1–2 to 10 nm. At the maximum vanadium content, VC nanocrystals have an anisotropic shape: they are extended in the direction perpendicular to the film–substrate interface.
Databáze: OpenAIRE