Aluminum Acetals in Organic Synthesis
| Autor: | Anne Boussonnière, Jacques Lebreton, Fabrice Dénès, Romain Bénéteau |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Organic Chemistry chemistry.chemical_element Ionic bonding 010402 general chemistry complex mixtures 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Aluminium Organic chemistry Organic synthesis Reactivity (chemistry) Physical and Theoretical Chemistry |
| Zdroj: | European Journal of Organic Chemistry. 2013:7853-7866 |
| ISSN: | 1434-193X |
| DOI: | 10.1002/ejoc.201300624 |
| Popis: | Aluminum acetals are easily obtained from esters and lactones by reduction with aluminum hydrides. These thermally unstable tetrahedral intermediates have found applications in organic synthesis, with various methodologies taking advantage both of the stabilities of these aluminum species at low temperatures and of their tendencies to undergo rearrangement into the corresponding aldehydes. Efficient one-pot transformations can be achieved from aluminum acetals under ionic and radical conditions. A comprehensive overview of the reactivity of these species, including the most recent advances in this field, is presented in this microreview. |
| Databáze: | OpenAIRE |
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