Structural, morphological, chemical, vibrational, pasting, rheological, and thermal characterization of isolated jicama (Pachyrhizus spp.) starch and jicama starch added with Ca(OH)2
Autor: | María de los Ángeles Cornejo-Villegas, Gilberto Vázquez-Contreras, Mario E. Rodríguez-García, Brenda Contreras-Jiménez, Alicia del Real-López |
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Rok vydání: | 2019 |
Předmět: |
Calcium hydroxide
biology Starch 010401 analytical chemistry 04 agricultural and veterinary sciences General Medicine Alkali metal biology.organism_classification 040401 food science 01 natural sciences Viscoelasticity 0104 chemical sciences Analytical Chemistry chemistry.chemical_compound symbols.namesake Crystallinity 0404 agricultural biotechnology chemistry Chemical engineering Rheology Pachyrhizus symbols van der Waals force Food Science |
Zdroj: | Food Chemistry. 283:83-91 |
ISSN: | 0308-8146 |
DOI: | 10.1016/j.foodchem.2019.01.013 |
Popis: | This work focused in the study of the changes on the physicochemical properties of isolated jicama starch (IJS), and IJS added with 0.15, 0.20, 0.30% Ca(OH)2 w/w. including: the structural, morphological, chemical, vibrational, pasting, rheological, and thermal characteristics. K, Ca, Na, and P were found in IJS. X-ray patterns, which showed that nanocrystals form the IJS according to the PDF-4 simulation. The functional properties were affected by the Ca inclusion, which originated electrostatic interactions. The gelatinization temperatures shifted to high values and exhibited an unfolding. The calculation of the IR absorption coefficient (β) of the gelatinized samples as a function of the Ca2+ for the C-OH showed that the Van der Waals interaction causes the changes in the rheological-mechanical properties. The SEM images demonstrated that starch without alkali exhibited a porous network structure, while the starch with lime exhibited flakes and porous network. The gels of Jicama starch with Ca(OH)2 showed a viscoelastic behavior (G′ > G″) with a reduction of their elastic module. |
Databáze: | OpenAIRE |
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